Rapid synthesis of Co, Ni co-doped ZnO nanoparticles: Optical and electrochemical properties

Abstract: We report for the first time a rapid preparation of Zn1-2xCoxNixO nanoparticles via a versatile and environmentally friendly route, microwave-assisted hydrothermal (MAH) method. The Co, Ni co-doped ZnO nanoparticles present an effect on photoluminescence and electrochemical properties, exhibiting excellent electrocatalytic performance compared to undoped ZnO sample. Photoluminescence spectroscopy measurements indicated the reduction of the green-orange-red visible emission region after adding Co and Ni ions, revealing the formation of alternative pathways for the generated recombination. The presence of these metallic ions into ZnO creates different defects, contributing to a local structural disorder, as revealed by Raman spectra. Electrochemical experiments revealed that the electrocatalytic oxidation of dopamine on ZnO attached to multi-walled carbon nanotubes improved significantly in the Co, Ni co-doped ZnO samples when compared to pure ZnO. (C) 2015 Elsevier Inc. All rights reserved.

Author(s):  Romeiro, FC; Marinho, JZ; Lemos, SCS; de Moura, AP; Freire, PG; da Silva, LE; Longo, E; Munoz, RAA; Lima, RC

JOURNAL OF SOLID STATE CHEMISTRY

DOI: 10.1016/j.jssc.2015.07.026