Magnetic properties of a polyfluorene derivative containing complexed neodymium ions

Abstract: Poly[9,9 ‘-dihexylfluorene-2,7-diyl)-6,6 ”-(2,2 ‘:6 ‘,2 ”-terpyridine)] (LaPPS75) and its complexes with neodymium were synthesized and characterized. Magnetic measurements showed that the noncomplexed polymer presented a ferromagnetic contribution due to the formation of pi stacking, and that in absence of those, the ferromagnetic behavior is suppressed. The pristine polymer, the complexed one and a low-molecular-weight model compound with the same structure of the complexed site in the parent polymer were studied. The observed behavior found is presented and discussed, the most important finding was that when a conjugated chain is used as a host for the metallic ion, an amplification of four times for the magnetization is achieved, using the same metallic content for complexed polymer and model compound for comparison. (c) 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019, 57, 304-311

Author(s):  Santana, AJ; Turchetti, DA; Zanlorenzi, C; Santos, JCR; Laureto, E; De Oliveira, AJA; Akcelrud, L

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS

DOI: 10.1002/polb.24785