Dual catalytic performance of arene-ruthenium amine complexes for norbornene ring-opening metathesis and methyl methacrylate atom-transfer radical polymerizations
Dual catalytic performance of arene-ruthenium amine complexes for norbornene ring-opening metathesis and methyl methacrylate atom-transfer radical polymerizations Abstract: Arene ruthenium(II) complexes bearing the cyclic amines RuCl2(eta(6)-p-cymene)(pyrrolidine)] (1), [RuCl2(eta(6)-p-cymene)(piperidine)] (2), and [RuCl2(eta(6)-p-cymene)(peridroazepine)] (3) were successfully synthesized. […]