PAAm/CMC/nanoclay nanocomposite hydrogel: understanding the influence of initiators on the chain-growth mechanisms Abstract: In this study, heat measurements were used to investigate the influence of three initiators on the chain-growth mechanisms of polyacrylamide/carboxymethylcellulose/nanoclay nanocomposite hydrogels. […]
Dual catalytic performance of arene-ruthenium amine complexes for norbornene ring-opening metathesis and methyl methacrylate atom-transfer radical polymerizations Abstract: Arene ruthenium(II) complexes bearing the cyclic amines RuCl2(eta(6)-p-cymene)(pyrrolidine)] (1), [RuCl2(eta(6)-p-cymene)(piperidine)] (2), and [RuCl2(eta(6)-p-cymene)(peridroazepine)] (3) were successfully synthesized. […]
Cyclic amines homobimetallic ruthenium pre-catalysts bearing bidentate phosphine and their dual catalytic activity for the ring-opening metathesis and atom-radical polymerizations Abstract: A series of [RuCl(dppb)(mu-Cl)(3)Ru(dppb)(amine)] complexes, where amine is pyrrolidine (1), piperidine (2) or perhydroazepine […]
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