Visible light-induced radical polymerization of vinyl acetate mediated by organo-nickel N2O2 Schiff-base complexes Abstract: Four nickel(II) complexes with symmetrically substituted N2O2 tetradentate Schiff-base ligands, prepared from the 2:1 condensation of 3-tert-butyl-salicylaldehyde, and ethylenediamine (1), o-phenylenediamine (2), […]
Fabrication of Three-Dimensional Polymer-Brush Gradients within Elastomeric Supports by Cu0-Mediated Surface-Initiated ATRP Abstract: Cu0-mediated surface-initiated ATRP (Cu0 SI-ATRP) emerges as a versatile, oxygen-tolerant process to functionalize three-dimensional (3D), microporous supports forming single and multiple polymer-brush […]
Synthesis of cobalt(II)-alpha-diimines complexes and their activity as mediators in organometallic mediated radical polymerization of vinyl acetate Abstract: This study describes the synthesis and characterization of three alpha-diimine-cobalt complexes of the type [CoCl2(R-DAB)] (R-DAB = R-N=CH-CH=N-R; […]
Synthesis of cobalt(II)-α-diimines complexes and their activity as mediators in organometallic mediated radical polymerization of vinyl acetate Abstract: This study describes the synthesis and characterization of three α-diimine-cobalt complexes of the type [CoCl2(R-DAB)] (R-DAB = RNCHCHNR; R = Mes, Dipp […]
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