Optical phonon characteristics of an orthorhombic-transformed polymorph of CaTa2O6 single crystal fibre
Abstract: Infrared-reflectivity spectroscopy and micro-Raman scattering were used to determine the optical phonon features of orthorhombic calcium tantalite (CaTa2O6) single crystal fibres. The fibres, obtained by the Laser-Heated Pedestal Growth method, grew into an ordered cubic structure . Long-time annealing was used to induce a polymorphic transformation to an aeschynite orthorhombic structure (Pnma space group). The phase transformation led to the appearance of structural domains and micro-cracks, responsible for diffuse scattering and depolarization of the scattered light in the visible range, but not in the infrared region. Thus, polarized infrared spectroscopy could be performed within oriented single domains, with an appropriate microscope, allowing us to determine all relevant polar phonons of the orthorhombic CaTa2O6. The obtained phononic dielectric response, = 22.4 and <Qu × f > = 86 × 103 GHz, shows the appropriateness of the material for microwave applications. Totally symmetric Raman modes could be resolved by polarization, after re-polishing the cracked sample surface.
Author(s): Almeida, R. M.; Andreeta, M. R. B.; Hernandes, A. C.; et al.
Materials Research Express
Volume: 1 Issue: 1 Published: 2014
DOI: http://doi.org/10.1088/2053-1591/1/1/016304