Femtosecond-laser-irradiation-induced structural organization and crystallinity of Bi2WO6
Abstract: Controlling the structural organization and crystallinity of functional oxides is key to enhancing their performance in technological applications. In this work, we report a strong enhancement of the structural organization and crystallinity of Bi2WO6 samples synthetized by a microwave-assisted hydrothermal method after exposing them to femtosecond laser irradiation. X-ray diffraction, UV-vis and Raman spectroscopies, photoluminescence emissions, energy dispersive spectroscopy, field emission scanning electron microscopy, and transmission electron microscopy were employed to characterize the as-synthetized samples. To complement and rationalize the experimental results, first-principles calculations were employed to study the effects of femtosecond laser irradiation. Structural and electronic effects induced by femtosecond laser irradiation enhance the long-range crystallinity while decreasing the free carrier density, as it takes place in the amorphous and liquid states. These effects can be considered a clear cut case of surface-enhanced Raman scattering.
Author(s): Pinatti, IM; Gouveia, AF; Doñate-Buendía,C; Mínguez-Vega, G; Andrés,J; Longo,E
SCIENTIFIC REPORTS
Published: 12 March 2020
DOI: https://doi.org/10.1038/s41598-020-61524-y
