A DFT investigation of the role of oxygen vacancies on the structural, electronic and magnetic properties of ATiO3 (A = Mn, Fe, Ni) multiferroic materials

A DFT investigation of the role of oxygen vacancies on the structural, electronic and magnetic properties of ATiO₃ (A = Mn, Fe, Ni) multiferroic materials

Abstract: In order to achieve deep insight into the multiferroic behavior and electronic properties of intrinsic oxygen vacancies in ATiO₃ (A = Mn, Fe, Ni), first-principles calculations based on hybrid density functional theory were carried out for bulk and non-polar (110) surface models. We found that the formation of an oxygen vacancy is accompanied by structural and electronic disorders in the constituent clusters of [TiO₆] and [AO₆] in ATiO₃, that become [TiO₅] and [AO₅], respectively. This perturbation contributes to the generation of intermediary energy levels in the band gap region, thus narrowing the required excitation energy. In addition, the remaining electrons are mainly trapped in the empty 3d orbitals of the Ti cations neighboring the oxygen vacancy, generating [TiO₅]′ (3d¹) that mediates an antiferromagnetic to ferromagnetic transition in MnTiO₃ and FeTiO₃ materials. In particular, MnTiO₃ surfaces show exposed [TiO₄]′ species that are responsible for its half-metallic behavior. The present work provides compelling evidence that controlling oxygen vacancies can be a valuable strategy to tailor the multiferroic properties of ATiO₃ materials.